(2R*,4R*,7S*,10R*,12R*)-3,11,13,15-Tetra­oxa­penta­cyclo­[5.5.3.01,7.02,4.010,12]penta­deca-5,8-dien-14-one

نویسندگان

  • Goverdhan Mehta
  • Saikat Sen
  • C. S. Ananda Kumar
چکیده

The title compound, C11H8O5, features a 'skipped' diene, an anti-bis-(epoxide) and a cyclic carbonate, all embedded in a densely functionalized [4.4.3]propellane scaffold. The crystal packing of this diepoxide is effected primarily by C-H⋯O hydrogen bonds, which link the mol-ecules into tapes along the b axis. Inter-tape connectivity is brought about by centrosymmetrically disposed pairs of C⋯O contacts [3.183 (4) Å] between the C(δ+)=O(δ-) dipoles of neighbouring carbonate moieties.

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عنوان ژورنال:

دوره 69  شماره 

صفحات  -

تاریخ انتشار 2013